Time Zone – GMT-4 (America/New_York)
| 1 | Jabeur O. (1) | Parry D. | 2 : 0 |
| 2 | Korpatsch T. | Burrage J. (Q) | 2 : 0 |
| 3 | Avanesyan E. | Tauson C. | 0 : 2 |
| 4 | Zvonareva V. | Boulter K. (7) | 2 : 1 |
| 5 | Cirstea S. (3) | Liu C. | 2 : 1 |
| 6 | Siniakova K. | Mandlik E. (LL) | 2 : 0 |
| 7 | Podoroska N. | Wang Xiy. | 2 : 0 |
| 8 | Savinykh V. (Q) | Gracheva V. (5) | 2 : 0 |
| 9 | Bronzetti L. (8) | Teichmann J. (Q) | 2 : 0 |
| 10 | Yuan Y. | Baindl K. | 1 : 2 |
| 11 | Masarova R. (RET.) | Fruhvirtova L. | 1 : 1 |
| 12 | Hruncakova V. (Q) | Blinkova A. (4) | 0 : 2 |
| 13 | Rus A. (6) | Rakhimova K. | 1 : 2 |
| 14 | Shnaider D. | Bai Z. (Q) | 2 : 1 |
| 15 | Saville D. | Putintseva Y. | 0 : 2 |
| 16 | Friedsam A-L. (Q) | Kvitova P. (2) | 0 : 2 |
| 1 | Jabeur O. (1) | Korpatsch T. | 2 : 0 |
| 2 | Tauson C. (RET.) | Zvonareva V. | 0 : 1 |
| 3 | Cirstea S. (3) | Siniakova K. | 0 : 2 |
| 4 | Podoroska N. | Savinykh V. | 2 : 1 |
| 5 | Bronzetti L. (8) | Baindl K. | 2 : 0 |
| 6 | Fruhvirtova L. | Blinkova A. (4) | 2 : 1 |
| 7 | Rakhimova K. | Shnaider D. | 0 : 2 |
| 8 | Putintseva Y. | Kvitova P. (WO.) (2) |
| 1 | Jabeur O. (1) | Zvonareva V. | 2 : 1 |
| 2 | Siniakova K. | Podoroska N. | 0 : 2 |
| 3 | Bronzetti L. (8) | Fruhvirtova L. | 0 : 2 |
| 4 | Shnaider D. | Kvitova P. (2) | 2 : 1 |
| 1 | Jabeur O. (1) | Podoroska N. | 2 : 1 |
| 2 | Fruhvirtova L. | Shnaider D. | 0 : 2 |
| 1 | Jabeur O. (1) | Shnaider D. | 2 : 0 |
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