Time Zone – GMT-5 (America/New_York)
| 1 | Sabalenka A. (1) | Zvonareva V. (Q) | 2 : 0 |
| 2 | Kudermetova V. | Zheng Q. | 2 : 0 |
| 3 | Alexandrova E. | Samsonova L. | 2 : 0 |
| 4 | Siniakova K. | Gauff C. (5) | 0 : 2 |
| 5 | Garcia C. (3) | Lisicki S. | 2 : 0 |
| 6 | Fourlis J. (Q) | Wang Xin. (RET.) (Q) | 1 : 1 |
| 7 | Podoroska N. | Masarova R. | 2 : 1 |
| 8 | Pliskova Ka. | Kvitova P. (7) | 0 : 2 |
| 9 | Sakkari M. (6) | Cornet A. | 2 : 0 |
| 10 | Azarenka V. | Sasnovich A. | 0 : 2 |
| 11 | Andreescu B. | Vondrousova M. | 0 : 2 |
| 12 | Niemeier J. (Q) | Jabeur O. (4) | 2 : 0 |
| 13 | Kasatkina D. (8) | Avanesyan E. | 1 : 2 |
| 14 | Siegemund L. (Q) | Blinkova A. | 1 : 2 |
| 15 | Vekic D. | Gracheva V. | 2 : 0 |
| 16 | Kudermetova P. (Q) | Rybakina E. (2) | 0 : 2 |
| 1 | Sabalenka A. (1) | Kudermetova V. | 0 : 2 |
| 2 | Alexandrova E. | Gauff C. (5) | 2 : 0 |
| 3 | Garcia C. (3) | Fourlis J. | 2 : 0 |
| 4 | Podoroska N. | Kvitova P. (7) | 0 : 2 |
| 5 | Sakkari M. (6) | Sasnovich A. | 2 : 0 |
| 6 | Vondrousova M. | Niemeier J. (RET.) | 1 : 0 |
| 7 | Avanesyan E. | Blinkova A. | 2 : 1 |
| 8 | Vekic D. | Rybakina E. (2) | 2 : 1 |
| 1 | Kudermetova V. | Alexandrova E. (WO.) | |
| 2 | Garcia C. (3) | Kvitova P. (7) | 0 : 2 |
| 3 | Sakkari M. (6) | Vondrousova M. | 2 : 0 |
| 4 | Avanesyan E. | Vekic D. | 0 : 2 |
| 1 | Alexandrova E. | Kvitova P. (7) | 0 : 2 |
| 2 | Sakkari M. (6) | Vekic D. | 0 : 2 |
| 1 | Kvitova P. (7) | Vekic D. | 2 : 0 |
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