Time Zone – GMT-5 (America/New_York)
| 1 | Ostapenko J. (1) | Bye | |
| 2 | Tauson C. (Q) | Giorgi C. | 2 : 1 |
| 3 | Cristian J. (LL) | Podoroska N. | 2 : 0 |
| 4 | Burrage J. (Q) | Gracheva V. (7) | 2 : 0 |
| 5 | Mertens E. (4) | Bye | |
| 6 | Kerber A. (WC) | Bronzetti L. | 0 : 2 |
| 7 | Trevisan M. | Pavlyuchenkova A. | 0 : 2 |
| 8 | Boulter K. | Paolini J. (6) | 2 : 0 |
| 9 | Martic P. (8) | Siniakova K. | 1 : 2 |
| 10 | Burel C. | Kraus S. (WC) | 2 : 0 |
| 11 | Yastremska D. (WC) | Andreeva E. (Q) | 2 : 1 |
| 12 | Bye | Vekic D. (3) | |
| 13 | Potapova A. (5) | Errani S. (Q) | 2 : 0 |
| 14 | Stefanini L. (Q) | Cocciaretto E. | 0 : 2 |
| 15 | Blinkova A. | Niemeier J. (Q) | 0 : 2 |
| 16 | Bye | Alexandrova E. (2) |
| 1 | Ostapenko J. (1) | Tauson C. | 2 : 1 |
| 2 | Cristian J. | Burrage J. | 0 : 2 |
| 3 | Mertens E. (4) | Bronzetti L. | 2 : 0 |
| 4 | Pavlyuchenkova A. | Boulter K. | 2 : 0 |
| 5 | Siniakova K. | Burel C. | 1 : 2 |
| 6 | Yastremska D. | Vekic D. (3) | 0 : 2 |
| 7 | Potapova A. (5) | Cocciaretto E. | 2 : 1 |
| 8 | Niemeier J. | Alexandrova E. (2) | 0 : 2 |
| 1 | Ostapenko J. (1) | Burrage J. | 2 : 0 |
| 2 | Mertens E. (4) | Pavlyuchenkova A. | 0 : 2 |
| 3 | Burel C. | Vekic D. (3) | 0 : 2 |
| 4 | Potapova A. (5) | Alexandrova E. (2) | 0 : 2 |
| 1 | Ostapenko J. (1) | Pavlyuchenkova A. | 2 : 0 |
| 2 | Vekic D. (3) | Alexandrova E. (2) | 1 : 2 |
| 1 | Ostapenko J. (1) | Alexandrova E. (2) | 2 : 0 |
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