Time Zone – GMT-5 (America/New_York)
| 1 | Rus A. (1) | Minnen G. | 2 : 0 |
| 2 | Cornet A. (Q) | Wickmayer Y. | 2 : 1 |
| 3 | Todoni A. A. | Andreeva E. (Q) | 0 : 2 |
| 4 | Parks A. | Bogdan A. (8) | 0 : 2 |
| 5 | Podoroska N. (9) | Tauson C. | 0 : 2 |
| 6 | Bassols M. (Alt) | Cristian J. | 0 : 2 |
| 7 | Sevastova A. | Mitu A. | 2 : 0 |
| 8 | Korpatsch T. | Avanesyan E. (6) | 0 : 2 |
| 9 | Cocciaretto E. (5) | Arango E. (Q) | 2 : 0 |
| 10 | Dart H. (Q) | Bondar A. (LL) | 2 : 0 |
| 11 | Siegemund L. | Parrizas-Diaz N. | 0 : 2 |
| 12 | Waltert S. (Q) | Blinkova A. (3) | 0 : 2 |
| 13 | Tomova V. (7) | Osorio C. | 0 : 2 |
| 14 | Pliskova Ka. | Kraus S. (Q) | 2 : 0 |
| 15 | Errani S. | McNally C. | 2 : 0 |
| 16 | Bai Z. | Maria T. (2) | 0 : 2 |
| 1 | Rus A. (1) | Cornet A. | 2 : 1 |
| 2 | Andreeva E. | Bogdan A. (8) | 0 : 2 |
| 3 | Tauson C. | Cristian J. | 0 : 2 |
| 4 | Sevastova A. | Avanesyan E. (RET.) (6) | 1 : 1 |
| 5 | Cocciaretto E. (5) | Dart H. | 1 : 2 |
| 6 | Parrizas-Diaz N. | Blinkova A. (3) | 2 : 1 |
| 7 | Osorio C. | Pliskova Ka. | 0 : 2 |
| 8 | Errani S. | Maria T. (2) | 2 : 0 |
| 1 | Rus A. (1) | Bogdan A. (8) | 1 : 2 |
| 2 | Cristian J. | Sevastova A. | 2 : 0 |
| 3 | Dart H. | Parrizas-Diaz N. | 2 : 0 |
| 4 | Pliskova Ka. | Errani S. | 2 : 0 |
| 1 | Bogdan A. (8) | Cristian J. | 2 : 1 |
| 2 | Dart H. | Pliskova Ka. | 0 : 2 |
| 1 | Bogdan A. (8) | Pliskova Ka. | 0 : 2 |
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