Time Zone – GMT-5 (America/New_York)
| 1 | Alcaraz C. (1) | Cilic M. (PR) | 2 : 0 |
| 2 | Zhang Z. | Nardi L. (Q) | 0 : 2 |
| 3 | Marozsan F. | Dougaz A. (WC) | 2 : 0 |
| 4 | Lehecka J. | Dimitrov G. (7) | 2 : 0 |
| 5 | Djokovic N. (3) | Berrettini M. | 0 : 2 |
| 6 | Struff J-L. | Griekspoor T. | 0 : 2 |
| 7 | O'Connell C. (Q) | Habib H. (WC) | 2 : 0 |
| 8 | Popyrin A. | Draper J. (8) | 0 : 2 |
| 9 | Tsitsipas S. (6) | Medjedovic H. (SE) | 1 : 2 |
| 10 | Halys Q. (Q) | Auger-Aliassime F. | 1 : 2 |
| 11 | Bergs Z. | Bautista-Agut R. | 2 : 0 |
| 12 | Khachanov K. | Medvedev D. (4) | 1 : 2 |
| 13 | Rublev A. (5) | Bublik A. | 2 : 0 |
| 14 | Virtanen O. (LL) | Borges N. | 0 : 2 |
| 15 | Van De Zandschulp B. (Q) | Shelbayh A. (WC) | 2 : 0 |
| 16 | Safiullin R. | De Minaur A. (2) | 0 : 2 |
| 1 | Alcaraz C. (1) | Nardi L. | 2 : 1 |
| 2 | Marozsan F. | Lehecka J. | 0 : 2 |
| 3 | Berrettini M. | Griekspoor T. | 2 : 1 |
| 4 | O'Connell C. | Draper J. (8) | 0 : 2 |
| 5 | Medjedovic H. | Auger-Aliassime F. (WO.) | |
| 6 | Bergs Z. | Medvedev D. (4) | 0 : 2 |
| 7 | Rublev A. (5) | Borges N. | 2 : 0 |
| 8 | Van De Zandschulp B. | De Minaur A. (2) | 0 : 2 |
| 1 | Alcaraz C. (1) | Lehecka J. | 1 : 2 |
| 2 | Berrettini M. | Draper J. (8) | 1 : 2 |
| 3 | Auger-Aliassime F. | Medvedev D. (RET.) (4) | 1 : 0 |
| 4 | Rublev A. (5) | De Minaur A. (2) | 2 : 1 |
| 1 | Lehecka J. | Draper J. (8) | 1 : 2 |
| 2 | Auger-Aliassime F. | Rublev A. (5) | 1 : 2 |
| 1 | Draper J. (8) | Rublev A. (5) |
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